tfhjj688
09-05-22 0 Просмотров

runyvmat.com As the industry leader in phosphine ligands and catalysts for homogeneous catalysis, Solvay offers a range of phosphorus compounds used in a breadth of applications and markets. Our scalable phosphorus chemistry meets the unique requirements of reactions that are crucial to several manufacturing processes across markets and applications, including petrochemicals, life sciences, flavors and fragrances, agrochemicals, fine chemicals, and plastics and other polymers. And do you what is Phosphine Ligands? Phosphines are a three-valent phosphorus compound and act as a "soft" σ-donating ligand with an unshared electron pair. This gives solubilization and stabilization to organometallic complexes by forming complexes with various transition metal species including latter-period transition metals and others, and is also used for controlling the reactivity and selectivity of the transition metal promoted reactions. Electron density and bulkiness of phosphine ligands are greatly related to the reactivity of their forming metal complexes. Generally, the phosphine ligands with high electron density increase the reactivity of oxidative addition from a metal center, and their bulkiness improves the reductive elimination. For example, trialkylphosphines especially tert-butyl or cyclohexyl group substituted phosphines show the highest electron density while the electron density of triarylphosphines and phosphite are sequentially decreasing. On the other hand, as an index of the bulkiness of phosphine ligands, that of monodentate phosphine ligands shows the cone angle (θ) while bidentate phosphine ligands show the bite angle (ω). As the angle of the phosphine ligands is wider, their steric effect is greater and they are regarded as more bulky phosphine ligands. A monodentate phosphine ligand of tri(o-tolyl)phosphine, and bidentate phosphine ligands of 1,1'-bis(diphenylphosphino)ferrocene and Xantphos are known as representative bulky phosphine ligands. There are many different kinds of Phosphine Ligands, such as Chiral Phosphine Ligands, Chelated Phosphine Ligands, Biaryl Phosphine Ligand, Trisubstituted Phosphine Ligands and Other Phosphine Ligands. Homogeneous catalysis is an efficient alternative to its heterogeneous counterpart, and enables access to certain molecules that are not accessible through heterogeneous catalysis. Our high-performance phosphine ligands provide endless customization opportunities for catalytic processes. Phosphorus chemistry offers substantial diversity of structure, tunability and thermal stability, which leads to its use in many essential industries and an abundance of applications. A majority of Solvay's phosphorus technologies are available in liquid or solution form, which facilitates ease of handling and safe product stewardship. Solids are available if preferred. Produced via industry-recognized manufacturing processes, our phosphine ligands and catalysts can be manufactured at any scale. Solvay offers expertise and manufacturing wherewithal at any phase of the value chain, but specializes in developing ligand solutions from the initial R&D stage all the way to industrial-scale production and distribution.Except for Phosphine Ligands, there are also many other material Intermediate and Function Materials like Catalyst including Homogeneous Catalyst and Olefin Copolymerization Catalyst.  


Отправить сообщение

Похожие объявления

jiatongglass.com

jiatongglass.com Glass wine bottles have high transparency and resistance to corrosion, in contact with most chemicals will not change the nature of the material. Their manufacturing process is simple, and they have lots of advantages including freely…

Line Chemical Rotary Kiln suppliers

 Tongli Heavy Machinery Co.,Ltd established in 1958 year, is a member of the China Building Material Machinery Association, a leading enterprise of China Cement Machinery, on the vendor of designated manufacturers for coal industry mechanical and…

How Gasification Works

How Gasification Works Some of the most promising, attention-getting energy alternatives aren't revolutionary ideas. We all know about windmills and waterwheels, which have been around for centuries. Today, a variety of improvements, including…

Transformer: What is it? (Definition And Working Principle)

 Transformer: What is it? (Definition And Working Principle) What is a Transformer? A transformer is defined as a passive electrical device that transfers electrical energy from one circuit to another through the process of electromagnetic induction. It…

Automatic Packing Machine for sale

Description This set of automatic packing machine can feed the materials, then weighing, filling, packing according to your filling specification. It is mainly suitable for quantitative packaging of powder materials, such as: flour, milk powder, starch ,…

Пожаловаться на это объявление
Войти чтоб ответить

Поделиться


Profiler

Database (default) 0.269786 s
21.2344 kB
Исходный пункт Min Max Average Всего
SELECT `group_name`, `config_key`, `config_value` FROM `oc2_config` ORDER BY `group_name` ASC, `config_key` ASC (1)
0.079763 s
0.079763 s
0.079763 s
0.079763 s
0.8359 kB
0.8359 kB
0.8359 kB
0.8359 kB
SELECT `oc2_`.`id_crontab` AS `id_crontab`, `oc2_`.`name` AS `name`, `oc2_`.`period` AS `period`, `oc2_`.`callback` AS `callback`, `oc2_`.`params` AS `params`, `oc2_`.`description` AS `description`, `oc2_`.`date_created` AS `date_created`, `oc2_`.`date_started` AS `date_started`, `oc2_`.`date_finished` AS `date_finished`, `oc2_`.`date_next` AS `date_next`, `oc2_`.`times_executed` AS `times_executed`, `oc2_`.`output` AS `output`, `oc2_`.`running` AS `running`, `oc2_`.`active` AS `active` FROM `oc2_crontab` AS `oc2_` WHERE `active` = 1 AND (`date_next` <= '2024-11-07 20:42:24' OR `date_next` IS NULL) (1)
0.001993 s
0.001993 s
0.001993 s
0.001993 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT `oc2_category`.`id_category` AS `id_category`, `oc2_category`.`name` AS `name`, `oc2_category`.`order` AS `order`, `oc2_category`.`created` AS `created`, `oc2_category`.`id_category_parent` AS `id_category_parent`, `oc2_category`.`parent_deep` AS `parent_deep`, `oc2_category`.`seoname` AS `seoname`, `oc2_category`.`description` AS `description`, `oc2_category`.`price` AS `price`, `oc2_category`.`last_modified` AS `last_modified`, `oc2_category`.`has_image` AS `has_image` FROM `oc2_categories` AS `oc2_category` WHERE `seoname` = 'odezhda' LIMIT 1 (1)
0.000514 s
0.000514 s
0.000514 s
0.000514 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SHOW FULL COLUMNS FROM `oc2_ads` (1)
0.001660 s
0.001660 s
0.001660 s
0.001660 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT `oc2_ad`.`id_ad` AS `id_ad`, `oc2_ad`.`id_user` AS `id_user`, `oc2_ad`.`id_category` AS `id_category`, `oc2_ad`.`id_location` AS `id_location`, `oc2_ad`.`title` AS `title`, `oc2_ad`.`seotitle` AS `seotitle`, `oc2_ad`.`description` AS `description`, `oc2_ad`.`address` AS `address`, `oc2_ad`.`latitude` AS `latitude`, `oc2_ad`.`longitude` AS `longitude`, `oc2_ad`.`price` AS `price`, `oc2_ad`.`phone` AS `phone`, `oc2_ad`.`website` AS `website`, `oc2_ad`.`ip_address` AS `ip_address`, `oc2_ad`.`created` AS `created`, `oc2_ad`.`published` AS `published`, `oc2_ad`.`featured` AS `featured`, `oc2_ad`.`last_modified` AS `last_modified`, `oc2_ad`.`status` AS `status`, `oc2_ad`.`has_images` AS `has_images`, `oc2_ad`.`stock` AS `stock`, `oc2_ad`.`rate` AS `rate`, `oc2_ad`.`favorited` AS `favorited`, `oc2_ad`.`cf_doppole` AS `cf_doppole` FROM `oc2_ads` AS `oc2_ad` WHERE `seotitle` = 'runyvmat-com-1' LIMIT 1 (1)
0.000495 s
0.000495 s
0.000495 s
0.000495 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT `oc2_location`.`id_location` AS `id_location`, `oc2_location`.`name` AS `name`, `oc2_location`.`order` AS `order`, `oc2_location`.`id_location_parent` AS `id_location_parent`, `oc2_location`.`parent_deep` AS `parent_deep`, `oc2_location`.`seoname` AS `seoname`, `oc2_location`.`description` AS `description`, `oc2_location`.`last_modified` AS `last_modified`, `oc2_location`.`has_image` AS `has_image`, `oc2_location`.`latitude` AS `latitude`, `oc2_location`.`longitude` AS `longitude`, `oc2_location`.`id_geoname` AS `id_geoname`, `oc2_location`.`fcodename_geoname` AS `fcodename_geoname` FROM `oc2_locations` AS `oc2_location` WHERE `oc2_location`.`id_location` = '0' LIMIT 1 (7)
0.000301 s
0.000575 s
0.000347 s
0.002430 s
0.7031 kB
0.7031 kB
0.7031 kB
4.9219 kB
SELECT `oc2_location`.`id_location` AS `id_location`, `oc2_location`.`name` AS `name`, `oc2_location`.`order` AS `order`, `oc2_location`.`id_location_parent` AS `id_location_parent`, `oc2_location`.`parent_deep` AS `parent_deep`, `oc2_location`.`seoname` AS `seoname`, `oc2_location`.`description` AS `description`, `oc2_location`.`last_modified` AS `last_modified`, `oc2_location`.`has_image` AS `has_image`, `oc2_location`.`latitude` AS `latitude`, `oc2_location`.`longitude` AS `longitude`, `oc2_location`.`id_geoname` AS `id_geoname`, `oc2_location`.`fcodename_geoname` AS `fcodename_geoname` FROM `oc2_locations` AS `oc2_location` WHERE `seoname` IS NULL LIMIT 1 (1)
0.000316 s
0.000316 s
0.000316 s
0.000316 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT `oc2_ad`.`id_ad` AS `id_ad`, `oc2_ad`.`id_user` AS `id_user`, `oc2_ad`.`id_category` AS `id_category`, `oc2_ad`.`id_location` AS `id_location`, `oc2_ad`.`title` AS `title`, `oc2_ad`.`seotitle` AS `seotitle`, `oc2_ad`.`description` AS `description`, `oc2_ad`.`address` AS `address`, `oc2_ad`.`latitude` AS `latitude`, `oc2_ad`.`longitude` AS `longitude`, `oc2_ad`.`price` AS `price`, `oc2_ad`.`phone` AS `phone`, `oc2_ad`.`website` AS `website`, `oc2_ad`.`ip_address` AS `ip_address`, `oc2_ad`.`created` AS `created`, `oc2_ad`.`published` AS `published`, `oc2_ad`.`featured` AS `featured`, `oc2_ad`.`last_modified` AS `last_modified`, `oc2_ad`.`status` AS `status`, `oc2_ad`.`has_images` AS `has_images`, `oc2_ad`.`stock` AS `stock`, `oc2_ad`.`rate` AS `rate`, `oc2_ad`.`favorited` AS `favorited`, `oc2_ad`.`cf_doppole` AS `cf_doppole` FROM `oc2_ads` AS `oc2_ad` WHERE `seotitle` = 'runyvmat-com-1' AND `status` != 30 LIMIT 1 (1)
0.000828 s
0.000828 s
0.000828 s
0.000828 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT `oc2_category`.`id_category` AS `id_category`, `oc2_category`.`name` AS `name`, `oc2_category`.`order` AS `order`, `oc2_category`.`created` AS `created`, `oc2_category`.`id_category_parent` AS `id_category_parent`, `oc2_category`.`parent_deep` AS `parent_deep`, `oc2_category`.`seoname` AS `seoname`, `oc2_category`.`description` AS `description`, `oc2_category`.`price` AS `price`, `oc2_category`.`last_modified` AS `last_modified`, `oc2_category`.`has_image` AS `has_image` FROM `oc2_categories` AS `oc2_category` WHERE `oc2_category`.`id_category` = '2' LIMIT 1 (7)
0.000309 s
0.000640 s
0.000376 s
0.002629 s
0.7031 kB
0.7031 kB
0.7031 kB
4.9219 kB
SHOW FULL COLUMNS FROM `oc2_comments` (1)
0.001584 s
0.001584 s
0.001584 s
0.001584 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT COUNT(`oc2_comment`.`id_comment`) AS `records_found` FROM `oc2_comments` AS `oc2_comment` WHERE `id_ad` = '3912' AND `status` = 1 (1)
0.000708 s
0.000708 s
0.000708 s
0.000708 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT `oc2_comment`.`id_comment` AS `id_comment`, `oc2_comment`.`id_comment_parent` AS `id_comment_parent`, `oc2_comment`.`id_ad` AS `id_ad`, `oc2_comment`.`id_comment_tree` AS `id_comment_tree`, `oc2_comment`.`created` AS `created`, `oc2_comment`.`comment` AS `comment`, `oc2_comment`.`status` AS `status`, `oc2_comment`.`id_user` AS `id_user`, `oc2_comment`.`ip_address` AS `ip_address` FROM `oc2_comments` AS `oc2_comment` WHERE `id_ad` = '3912' AND `status` = 1 ORDER BY `created` ASC LIMIT 20 OFFSET 0 (1)
0.000659 s
0.000659 s
0.000659 s
0.000659 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT `oc2_c`.`id_category`, COUNT("a.id_ad") AS `count` FROM `oc2_categories` AS `oc2_c` JOIN `oc2_ads` AS `oc2_a` USING (`id_category`) WHERE `oc2_a`.`id_category` = oc2_c.id_category AND IF(0 <> 0, DATE_ADD( published, INTERVAL 0 DAY), DATE_ADD( NOW(), INTERVAL 1 DAY)) > '2024-11-07 20:42:25' AND `oc2_a`.`status` = 1 GROUP BY `oc2_c`.`id_category` ORDER BY `oc2_c`.`order` ASC (1)
0.036311 s
0.036311 s
0.036311 s
0.036311 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT `oc2_category`.`id_category` AS `id_category`, `oc2_category`.`name` AS `name`, `oc2_category`.`order` AS `order`, `oc2_category`.`created` AS `created`, `oc2_category`.`id_category_parent` AS `id_category_parent`, `oc2_category`.`parent_deep` AS `parent_deep`, `oc2_category`.`seoname` AS `seoname`, `oc2_category`.`description` AS `description`, `oc2_category`.`price` AS `price`, `oc2_category`.`last_modified` AS `last_modified`, `oc2_category`.`has_image` AS `has_image` FROM `oc2_categories` AS `oc2_category` WHERE `id_category` != 1 AND `parent_deep` IN (0, 1) ORDER BY `order` ASC (1)
0.002016 s
0.002016 s
0.002016 s
0.002016 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT `oc2_category`.`id_category` AS `id_category`, `oc2_category`.`name` AS `name`, `oc2_category`.`order` AS `order`, `oc2_category`.`created` AS `created`, `oc2_category`.`id_category_parent` AS `id_category_parent`, `oc2_category`.`parent_deep` AS `parent_deep`, `oc2_category`.`seoname` AS `seoname`, `oc2_category`.`description` AS `description`, `oc2_category`.`price` AS `price`, `oc2_category`.`last_modified` AS `last_modified`, `oc2_category`.`has_image` AS `has_image` FROM `oc2_categories` AS `oc2_category` WHERE `id_category_parent` = '2' AND `id_category` != '2' LIMIT 1 (1)
0.002512 s
0.002512 s
0.002512 s
0.002512 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SHOW FULL COLUMNS FROM `oc2_users` (1)
0.001600 s
0.001600 s
0.001600 s
0.001600 s
0.7109 kB
0.7109 kB
0.7109 kB
0.7109 kB
SELECT `oc2_user`.`id_user` AS `id_user`, `oc2_user`.`name` AS `name`, `oc2_user`.`seoname` AS `seoname`, `oc2_user`.`email` AS `email`, `oc2_user`.`password` AS `password`, `oc2_user`.`description` AS `description`, `oc2_user`.`status` AS `status`, `oc2_user`.`id_role` AS `id_role`, `oc2_user`.`id_location` AS `id_location`, `oc2_user`.`created` AS `created`, `oc2_user`.`last_modified` AS `last_modified`, `oc2_user`.`logins` AS `logins`, `oc2_user`.`last_login` AS `last_login`, `oc2_user`.`last_ip` AS `last_ip`, `oc2_user`.`user_agent` AS `user_agent`, `oc2_user`.`token` AS `token`, `oc2_user`.`token_created` AS `token_created`, `oc2_user`.`token_expires` AS `token_expires`, `oc2_user`.`api_token` AS `api_token`, `oc2_user`.`hybridauth_provider_name` AS `hybridauth_provider_name`, `oc2_user`.`hybridauth_provider_uid` AS `hybridauth_provider_uid`, `oc2_user`.`subscriber` AS `subscriber`, `oc2_user`.`rate` AS `rate`, `oc2_user`.`has_image` AS `has_image`, `oc2_user`.`failed_attempts` AS `failed_attempts`, `oc2_user`.`last_failed` AS `last_failed`, `oc2_user`.`notification_date` AS `notification_date`, `oc2_user`.`device_id` AS `device_id`, `oc2_user`.`stripe_user_id` AS `stripe_user_id`, `oc2_user`.`google_authenticator` AS `google_authenticator` FROM `oc2_users` AS `oc2_user` WHERE `oc2_user`.`id_user` = '32458' LIMIT 1 (1)
0.001455 s
0.001455 s
0.001455 s
0.001455 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
SELECT `oc2_ad`.`id_ad` AS `id_ad`, `oc2_ad`.`id_user` AS `id_user`, `oc2_ad`.`id_category` AS `id_category`, `oc2_ad`.`id_location` AS `id_location`, `oc2_ad`.`title` AS `title`, `oc2_ad`.`seotitle` AS `seotitle`, `oc2_ad`.`description` AS `description`, `oc2_ad`.`address` AS `address`, `oc2_ad`.`latitude` AS `latitude`, `oc2_ad`.`longitude` AS `longitude`, `oc2_ad`.`price` AS `price`, `oc2_ad`.`phone` AS `phone`, `oc2_ad`.`website` AS `website`, `oc2_ad`.`ip_address` AS `ip_address`, `oc2_ad`.`created` AS `created`, `oc2_ad`.`published` AS `published`, `oc2_ad`.`featured` AS `featured`, `oc2_ad`.`last_modified` AS `last_modified`, `oc2_ad`.`status` AS `status`, `oc2_ad`.`has_images` AS `has_images`, `oc2_ad`.`stock` AS `stock`, `oc2_ad`.`rate` AS `rate`, `oc2_ad`.`favorited` AS `favorited`, `oc2_ad`.`cf_doppole` AS `cf_doppole` FROM `oc2_ads` AS `oc2_ad` WHERE (`id_category` = '2' OR `id_location` = '0') AND `id_ad` != '3912' AND `status` = 1 ORDER BY RAND() LIMIT 5 (1)
0.132313 s
0.132313 s
0.132313 s
0.132313 s
0.7031 kB
0.7031 kB
0.7031 kB
0.7031 kB
Kohana 0.027789 s
144.0000 kB
Исходный пункт Min Max Average Всего
find_file (220)
0.000013 s
0.014074 s
0.000126 s
0.027789 s
0.4453 kB
3.2109 kB
0.6545 kB
144.0000 kB
Requests 2.506073 s
1,772.9844 kB
Исходный пункт Min Max Average Всего
"odezhda/runyvmat-com-1.html" (1)
2.508298 s
2.508298 s
2.508298 s
2.508298 s
1,795.2891 kB
1,795.2891 kB
1,795.2891 kB
1,795.2891 kB
Запуск приложения (1) 5.495423 s 5.495423 s 5.495423 s 5.495423 s
3,626.9453 kB 3,626.9453 kB 3,626.9453 kB 3,626.9453 kB

Окружающая среда

Включённые файлы (194)

Загруженые расширения (64)

$_SESSION

$_SERVER